Name: Valentini Grammatikopoulou
Country: Greece
Birthdate: 09.02.97, 28 years
WTA ranking: 546
TOP ranking's position: 143 (29.08.22, 43900 points)
Points: 84
Prize money: 923.607 $
Matches total: 743
Win: 429
%: 57.74 %
Country: Greece
Birthdate: 09.02.97, 28 years
WTA ranking: 546
TOP ranking's position: 143 (29.08.22, 43900 points)
Points: 84
Prize money: 923.607 $
Matches total: 743
Win: 429
%: 57.74 %
| year | summary | Hard | Clay | I. hard | Carpet | Grass | Acrylic |
| 2025 | 7/11 | 5/6 | 0/0 | 1/3 | 1/2 | 0/0 | 0/0 |
| 2024 | 20/27 | 3/7 | 9/13 | 3/4 | 5/2 | 0/1 | 0/0 |
| 2023 | 38/33 | 9/9 | 25/17 | 4/5 | 0/0 | 0/2 | 0/0 |
| 2022 | 25/29 | 11/9 | 9/10 | 4/7 | 0/0 | 1/3 | 0/0 |
| 2021 | 30/25 | 11/6 | 16/12 | 2/6 | 1/1 | 0/0 | 0/0 |
| 2020 | 18/11 | 1/2 | 8/3 | 9/6 | 0/0 | 0/0 | 0/0 |
| 2019 | 25/32 | 9/10 | 10/13 | 2/6 | 3/1 | 1/2 | 0/0 |
| 2018 | 41/30 | 18/11 | 14/9 | 6/6 | 1/2 | 2/2 | 0/0 |
| 2017 | 30/25 | 13/10 | 12/8 | 4/4 | 0/1 | 1/2 | 0/0 |
| 2016 | 57/27 | 9/3 | 33/16 | 11/6 | 4/2 | 0/0 | 0/0 |
| 2015 | 57/19 | 35/6 | 19/9 | 2/3 | 1/1 | 0/0 | 0/0 |
| 2014 | 39/20 | 19/8 | 20/12 | 0/0 | 0/0 | 0/0 | 0/0 |
| 2013 | 26/12 | 0/0 | 10/7 | 0/0 | 16/5 | 0/0 | 0/0 |
| 2012 | 16/11 | 1/2 | 10/5 | 0/0 | 5/4 | 0/0 | 0/0 |
| 2011 | 0/2 | 0/1 | 0/0 | 0/0 | 0/1 | 0/0 | 0/0 |
| TOTAL | 429/314 | 144/90 | 195/134 | 48/56 | 37/22 | 5/12 | 0/0 |
| perc. % | 57.74 % | 61.54 % | 59.27 % | 46.15 % | 62.71 % | 29.41 % | 0 % |
Valentini Grammatikopoulou / Fixtures
| no matches found |
Valentini Grammatikopoulou form / surface: Clay
Valentini Grammatikopoulou / surface: Clay
| 24.09.24 | 1st round | Cristina Diaz Adrover | Valentini Grammatikopoulou | 6-2, 6-4 |  | match details |  W35 Santa | Clay |
| 30.08.24 | 3rd round | Sarah Tatu | Valentini Grammatikopoulou | 6-3, 2-6, 7-5 | | match details |  W35 Brasov | Clay |
| 28.08.24 | 2nd round | Valentini Grammatikopoulou | Victoria Muntean | 5-7, 7-66, 6-4 |  | match details | ||
| 14.08.24 | 2nd round | Ekaterina Ovcharenko | Valentini Grammatikopoulou | 6-4, 6-0 | | match details |  W75 Kursumlijska | Clay |
| 21.06.24 | 1/4 | Carolina Kuhl | Valentini Grammatikopoulou | 6-2, 6-4 | | match details |  W75 Olomouc | Clay |
| 20.06.24 | 2nd round | Valentini Grammatikopoulou | Julia Avdeeva | 7-65, 7-63 | | match details | ||
| 19.06.24 | 1st round | Valentini Grammatikopoulou | Amina Anshba | 6-1, 6-2 | | match details | ||
| 20.05.24 | q 1 | Hailey Baptiste | Valentini Grammatikopoulou | 3-6, 6-4, 6-3 | | match details |  Paris | Clay |
| 28.05.24 | 1st round | Julie Belgraver | Valentini Grammatikopoulou | 6-2, 6-2 | | match details |  W35 Klagenfurt | Clay |
| 01.05.24 | 1st round | Louisa Chirico | Valentini Grammatikopoulou | 7-5, 7-5 | | match details |  W100 Bonita | Clay |
| 26.04.24 | 1/4 | Louisa Chirico | Valentini Grammatikopoulou | 4-6, 6-3, 6-3 | | match details | W75 Charlottesville | Clay |
| 25.04.24 | 2nd round | Valentini Grammatikopoulou | Kathinka Von Deichmann | 1-6, 6-2, 6-3 | | match details | ||
| 24.04.24 | 1st round | Valentini Grammatikopoulou | Fanny Stollar | 6-2, 7-5 | | match details | ||
| 17.04.24 | 1st round | Ikumi Yamazaki | Valentini Grammatikopoulou | 6-4, 7-5 | | match details |  W35 Hammamet | Clay |
| 12.04.24 | Rubber 1 | Johanne Svendsen | Valentini Grammatikopoulou | 7-64, 4-6, 6-3 | | match details |  Billie Jean | Clay |
| 11.04.24 | Rubber 1 | Valentini Grammatikopoulou | Daniela Vismane | 6-0, 7-5 | | match details | ||
| 10.04.24 | Rubber 1 | Valentini Grammatikopoulou | Emily Sartz-Lunde | 6-3, 2-6, 6-4 | | match details | ||
| 09.04.24 | Mia Ristic | Valentini Grammatikopoulou | 2-6, 6-4, 6-1 | | match details | |||
| 08.04.24 | Caijsa Wilda Hennemann | Valentini Grammatikopoulou | 6-4, 3-6, 6-4 | | match details | |||
| 04.04.24 | 1/4 | Panna Udvardy | Valentini Grammatikopoulou | 6-1, 4-6, 6-4 | | match details |  W75 Split | Clay |
| 03.04.24 | 2nd round | Valentini Grammatikopoulou | Veronica Miroshnichenko | 6-2, 6-1 | | match details | ||
| 02.04.24 | 1st round | Valentini Grammatikopoulou | Carole Monnet | 6-1, 6-1 | | match details | ||
| 04.12.23 | 1st round | Daria Lodikova | Valentini Grammatikopoulou | 7-65, 6-2 | | match details |  Uruguay | Clay |
| 28.11.23 | 1st round | Ipek Oz | Valentini Grammatikopoulou | 7-61, 6-0 | | match details |  Buenos Aires | Clay |
| 22.11.23 | 1st round | Leyre Romero Gormaz | Valentini Grammatikopoulou | 6-4, 1-6, 6-3 | | match details |  W100 Valencia | Clay |
| 23.09.23 | 1/2 | Ekaterina Makarova (1996) | Valentini Grammatikopoulou | 6-3, 6-0 | | match details | W25 Slobozia | Clay |
| 22.09.23 | 1/4 | Valentini Grammatikopoulou | Anca Alexia Todoni | 6-1, 1-0, Anca Alexia Todoni - retired | | match details | ||
| 21.09.23 | 2nd round | Valentini Grammatikopoulou | Viktoriia Dema | 4-6, 6-2, 6-3 | | match details | ||
| 19.09.23 | 1st round | Valentini Grammatikopoulou | Tiphanie Lemaitre | 6-2, 5-7, 3-1, Tiphanie Lemaitre - retired | | match details | ||
| 12.09.23 | 1st round | Anna Bondar | Valentini Grammatikopoulou | 6-3, 2-6, 6-4 | | match details | Bucharest | Clay |
| 06.09.23 | 2nd round | Alize Cornet | Valentini Grammatikopoulou | 4-6, 6-4, 7-5 | | match details | Bari | Clay |
| 05.09.23 | 1st round | Valentini Grammatikopoulou | Georgia Pedone | 6-4, 6-2 | | match details | ||
| 05.08.23 | 1/2 | Hanne Vandewinkel | Valentini Grammatikopoulou | 6-3, 6-3 | | match details |  W25 Koge | Clay |
| 04.08.23 | 1/4 | Valentini Grammatikopoulou | Dejana Radanovic | 1-6, 6-3, 6-4 | | match details | ||
| 03.08.23 | 2nd round | Valentini Grammatikopoulou | Anouk Koevermans | 1-6, 7-69, 6-2 | | match details | ||
| 02.08.23 | 1st round | Valentini Grammatikopoulou | Anca Alexia Todoni | 6-2, 7-64 | | match details | ||
| 25.07.23 | 1st round | Dalila Jakupovic | Valentini Grammatikopoulou | 7-611, 6-2 | | match details |  Lausanne | Clay |
| 24.07.23 | qual. | Valentini Grammatikopoulou | Valentina Ryser | 6-1, 6-3 | | match details | ||
| 18.07.23 | 1st round | Tamara Korpatsch | Valentini Grammatikopoulou | 6-4, 6-4 | | match details |  Budapest | Clay |
| 16.07.23 | qual. | Astra Sharma | Valentini Grammatikopoulou | 6-3, 6-1 | | match details | ||
| 15.07.23 | q 1 | Valentini Grammatikopoulou | Adrienn Nagy | 6-2, 3-6, 6-4 | | match details | ||
| 10.07.23 | 1st round | Aleksandra Krunic | Valentini Grammatikopoulou | 6-2, 3-6, 6-4 | | match details | Contrexeville | Clay |
| 05.07.23 | 2nd round | Dejana Radanovic | Valentini Grammatikopoulou | 7-62, 6-2 | | match details |  W60 Liepaja | Clay |
| 09.06.23 | 1/4 | Dimitra Pavlou | Valentini Grammatikopoulou | 7-5, 6-3 | | match details | W25 Kursumlijska | Clay |
| 08.06.23 | 2nd round | Valentini Grammatikopoulou | Aysegul Mert | 6-3, 6-2 | | match details | ||
| 07.06.23 | 1st round | Valentini Grammatikopoulou | Sandra Samir | 6-3, 6-1 | | match details | ||
| 04.06.23 | fin | Valentini Grammatikopoulou | Rebecca Sramkova | 6-4, 6-4 | | match details |  W40 Otocec | Clay |
| 03.06.23 | 1/2 | Valentini Grammatikopoulou | Ilinca Dalina Amariei | 6-4, 4-6, 7-62 | | match details | ||
| 02.06.23 | 1/4 | Valentini Grammatikopoulou | Seone Mendez | 6-3, 1-6, 6-4 | | match details | ||
| 01.06.23 | 3rd round | Valentini Grammatikopoulou | Dimitra Pavlou | 4-6, 6-1, 6-2 | | match details | ||
| 31.05.23 | 2nd round | Valentini Grammatikopoulou | Gina Feistel | 3-6, 6-1, 6-4 | | match details | ||
| 24.05.23 | q 2 | Nao Hibino | Valentini Grammatikopoulou | 6-1, 6-1 | | match details | Paris | Clay |
| 22.05.23 | q 1 | Valentini Grammatikopoulou | Sinja Kraus | 6-4, 6-1 | | match details | ||
| 10.05.23 | 2nd round | Diane Parry | Valentini Grammatikopoulou | 6-4, 6-71, 6-1 | | match details | W60 Zagreb | Clay |
| 09.05.23 | 1st round | Valentini Grammatikopoulou | Maja Chwalinska | 7-5, 5-7, 6-4 | | match details | ||
| 07.05.23 | fin | Valentini Grammatikopoulou | Kathinka Von Deichmann | 6-4, 6-1 | | match details | W25 Santa | Clay |
| 06.05.23 | 1/2 | Valentini Grammatikopoulou | Federica Bilardo | 6-3, 6-2 | | match details | ||
| 05.05.23 | 1/4 | Valentini Grammatikopoulou | Anastasia Abbagnato | 6-3, 6-4 | | match details | ||
| 04.05.23 | 2nd round | Valentini Grammatikopoulou | Claudia Hoste Ferrer | 6-1, 7-5 | | match details | ||
| 03.05.23 | 1st round | Valentini Grammatikopoulou | Margherita Marcon | 6-2, 6-0 | | match details | ||
| 19.04.23 | 2nd round | Zeynep Sonmez | Valentini Grammatikopoulou | 6-2, 6-1 | | match details | W60 Bellinzona | Clay |
| 07.04.23 | 1/4 | Weronika Falkowska | Valentini Grammatikopoulou | 4-6, 6-4, 6-2 | | match details | W25 Santa | Clay |
| 06.04.23 | 2nd round | Valentini Grammatikopoulou | Georgia Pedone | 7-64, 6-4 | | match details | ||
| 05.04.23 | 1st round | Valentini Grammatikopoulou | Lois Boisson | 2-6, 6-4, 6-1 | | match details | ||
| 15.07.22 | 1/4 | Anna Siskova | Valentini Grammatikopoulou | 7-68, 7-5 | | match details | W60 Liepaja | Clay |
| 14.07.22 | 2nd round | Valentini Grammatikopoulou | Beatrise Zeltina | 6-1, 6-1 | | match details | ||
| 13.07.22 | 1st round | Valentini Grammatikopoulou | Marine Partaud | 4-6, 6-3, 7-63 | | match details | ||
| 05.07.22 | 1st round | Panna Udvardy | Valentini Grammatikopoulou | 6-2, 7-5 | | match details |  Bastad | Clay |
| 23.05.22 | 1st round | Daria Saville | Valentini Grammatikopoulou | 6-1, 6-2 | | match details | Paris | Clay |
| 20.05.22 | qual. | Valentini Grammatikopoulou | Christina Mchale | 6-3, 6-3 | | match details | ||
| 18.05.22 | q 2 | Valentini Grammatikopoulou | Isabella Shinikova | 2-6, 6-0, 6-3 | | match details | ||
| 17.05.22 | q 1 | Valentini Grammatikopoulou | Valeria Savinykh | 6-4, 6-1 | | match details | ||
| 11.05.22 | 1st round | Sada Nahimana | Valentini Grammatikopoulou | 6-4, 6-4 | | match details | W60 Saint | Clay |
| 02.05.22 | 1st round | Susan Bandecchi | Valentini Grammatikopoulou | 6-4, 6-2 | | match details | W60 Prague | Clay |
| 29.04.22 | 1/4 | Weronika Falkowska | Valentini Grammatikopoulou | 6-3, 1-6, 6-0 | | match details |  W25 Cairo | Clay |
| 28.04.22 | 2nd round | Valentini Grammatikopoulou | Antonia Schmidt | 6-3, 6-0 | | match details | ||
| 27.04.22 | 1st round | Valentini Grammatikopoulou | Melanie Klaffner | 6-2, 4-6, 6-4 | | match details | ||
| 20.04.22 | 1st round | Xiyu Wang | Valentini Grammatikopoulou | 6-3, 6-0 | | match details | W60 Charlottesville | Clay |
| 14.04.22 | 2nd round | Grace Min | Valentini Grammatikopoulou | 7-5, 6-2 | | match details | W100 Palm | Clay |
| 13.04.22 | 1st round | Valentini Grammatikopoulou | Whitney Osuigwe | 4-6, 6-2, 6-4 | | match details | ||
| 03.04.22 | qual. | Ipek Oz | Valentini Grammatikopoulou | 7-5, 6-4 | | match details |  Bogota | Clay |
| 02.04.22 | q 1 | Valentini Grammatikopoulou | Maria Paulina Perez Garcia | 6-3, 6-3 | | match details | ||
| 26.01.22 | 1st round | Anastasia Nefedova | Valentini Grammatikopoulou | 5-7, 7-67, 6-4 | | match details | W25 Cairo | Clay |
| 12.08.21 | 2nd round | Magali Kempen | Valentini Grammatikopoulou | 6-4, 6-3 | | match details |  W25 Koksijde | Clay |
| 10.08.21 | 1st round | Valentini Grammatikopoulou | Victoria Bosio | 6-3, 6-0 | | match details | ||
| 01.08.21 | q 1 | Paula Ormaechea | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | Cluj-Napoca | Clay |
| 26.07.21 | fin | Valentini Grammatikopoulou | Tessah Andrianjafitrimo | 7-5, 6-4 | | match details |  W25 Telavi | Clay |
| 24.07.21 | 1/4 | Valentini Grammatikopoulou | Justina Mikulskyte | 6-3, 2-1, Justina Mikulskyte - retired | | match details | ||
| 24.07.21 | 1/2 | Valentini Grammatikopoulou | Fernanda Contreras Gomez | 6-0, 6-2 | | match details | ||
| 23.07.21 | 3rd round | Valentini Grammatikopoulou | Victoria Bosio | 6-1, 6-4 | | match details | ||
| 21.07.21 | 2nd round | Valentini Grammatikopoulou | Elena Malygina | 6-3, 4-6, 6-4 | | match details | ||
| 14.07.21 | 1st round | Jasmine Paolini | Valentini Grammatikopoulou | 6-3, 4-6, 7-5 | | match details | Lausanne | Clay |
| 12.07.21 | qual. | Valentini Grammatikopoulou | Jesika Maleckova | 6-3, 6-71, 6-2 | | match details | ||
| 08.07.21 | 2nd round | Suzan Lamens | Valentini Grammatikopoulou | 4-6, 6-2, 6-1 | | match details |  W60 Amstelveen | Clay |
| 07.07.21 | 1st round | Valentini Grammatikopoulou | Ipek Oz | 6-2, 5-7, 6-3 | | match details | ||
| 01.07.21 | 2nd round | Arianne Hartono | Valentini Grammatikopoulou | 6-2, 6-1 | | match details | W25 The | Clay |
| 30.06.21 | 1st round | Valentini Grammatikopoulou | Tatiana Pieri | 6-2, 6-1 | | match details | ||
| 15.06.21 | qual. | Andreea Prisacariu | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | W60 Stare | Clay |
| 14.06.21 | q 1 | Valentini Grammatikopoulou | Laetitia Pulchartova | 4-6, 6-2, 10-7 | | match details | ||
| 28.05.21 | 2nd round | Malene Helgo | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | W25 Liepaja | Clay |
| 26.05.21 | 1st round | Valentini Grammatikopoulou | Vanda Lukacs | 6-0, 2-1, Vanda Lukacs - retired | | match details | ||
| 30.04.21 | 1/4 | Maria Gutierrez Carrasco | Valentini Grammatikopoulou | 6-71, 7-66, 6-3 | | match details | W25 Oeiras | Clay |
| 29.04.21 | 3rd round | Valentini Grammatikopoulou | Conny Perrin | 6-4, 6-2 | | match details | ||
| 28.04.21 | 2nd round | Valentini Grammatikopoulou | Ivonne Cavalle-Reimers | 6-4, 6-0 | | match details | ||
| 15.04.21 | 2nd round | Valentini Grammatikopoulou | Francesca Jones | 6-3, 4-6, 6-3 | | match details | W60 Oeiras | Clay |
| 15.04.21 | 2nd round | Francesca Jones | Valentini Grammatikopoulou | 6-3, 4-6, 6-3 | | match details | ||
| 13.04.21 | 1st round | Valentini Grammatikopoulou | Federica Di Sarra | 6-1, 6-2 | | match details | ||
| 07.04.21 | 1st round | Ivonne Cavalle-Reimers | Valentini Grammatikopoulou | 6-2, 6-71, 6-2 | | match details | W25 Cordoba | Clay |
| 01.04.21 | 2nd round | Maria Lourdes Carle | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | W25 Villa | Clay |
| 30.03.21 | 1st round | Valentini Grammatikopoulou | Laura Pigossi | 6-3, 7-5 | | match details | ||
| 24.03.21 | 1st round | Panna Udvardy | Valentini Grammatikopoulou | 6-1, 6-4 | | match details | W25 Buenos | Clay |
| 26.09.20 | 1/2 | Grace Min | Valentini Grammatikopoulou | 6-2, 6-3 | | match details | W25 Prerov | Clay |
| 25.09.20 | 1/4 | Valentini Grammatikopoulou | Suzan Lamens | 6-3, 6-2 | | match details | ||
| 24.09.20 | 2nd round | Valentini Grammatikopoulou | Elizabeth Halbauer | 6-0, 6-3 | | match details | ||
| 22.09.20 | 1st round | Valentini Grammatikopoulou | Anna Siskova | 6-4, 6-2 | | match details | ||
| 17.09.20 | 2nd round | Andreea Rosca | Valentini Grammatikopoulou | 7-5, 1-6, 6-3 | | match details | W25 Zagreb | Clay |
| 15.09.20 | 1st round | Valentini Grammatikopoulou | Allie Kiick | 3-6, 6-4, 3-0, Allie Kiick - retired | | match details | ||
| 03.09.20 | 4th round | Anna Schmiedlova | Valentini Grammatikopoulou | 6-3, 6-0 | | match details | Prague | Clay |
| 02.09.20 | 3rd round | Valentini Grammatikopoulou | Robin Anderson | 3-6, 6-4, 6-3 | | match details | ||
| 01.09.20 | 2nd round | Valentini Grammatikopoulou | Martina Trevisan | 6-2, 6-1 | | match details | ||
| 31.08.20 | 1st round | Valentini Grammatikopoulou | Nuria Parrizas-Diaz | 6-4, 6-1 | | match details | ||
| 11.03.20 | 1st round | Valentini Grammatikopoulou | Karin Kennel | 2-6, 7-61, 7-65 | | match details |  W25 Olimpia | Clay |
| 07.11.19 | 2nd round | Elisabetta Cocciaretto | Valentini Grammatikopoulou | 7-5, 6-3 | | match details |  W60 Colina | Clay |
| 06.11.19 | 1st round | Valentini Grammatikopoulou | Andrea Gamiz | 7-5, 2-6, 7-5 | | match details | ||
| 30.10.19 | 1st round | Teliana Pereira | Valentini Grammatikopoulou | 6-3, 6-2 | | match details |  W60 Asuncion | Clay |
| 20.09.19 | 1/4 | Amina Anshba | Valentini Grammatikopoulou | 7-5, 7-64 | | match details |  W25 Podgorica | Clay |
| 19.09.19 | 2nd round | Valentini Grammatikopoulou | Anastasia Detiuc | 4-6, 6-2, 7-64 | | match details | ||
| 18.09.19 | 1st round | Valentini Grammatikopoulou | Nika Radisic | 6-4, 6-1 | | match details | ||
| 11.09.19 | 1st round | Katharina Gerlach | Valentini Grammatikopoulou | 6-0, 6-2 | | match details | W25 Frydek | Clay |
| 06.09.19 | 1/4 | Lucrezia Stefanini | Valentini Grammatikopoulou | 6-1, 6-0 | | match details | W25 Trieste | Clay |
| 05.09.19 | 2nd round | Valentini Grammatikopoulou | Camilla Rosatello | 6-4, 7-5 | | match details | ||
| 04.09.19 | 1st round | Valentini Grammatikopoulou | Lisa Ponomar | 6-2, 6-0 | | match details | ||
| 13.07.19 | q 1 | Pauline Wuarin | Valentini Grammatikopoulou | 1-6, 6-4, 6-3 | | match details | Lausanne | Clay |
| 11.07.19 | 2nd round | Louisa Chirico | Valentini Grammatikopoulou | 6-4, 2-6, 7-63 | | match details |  W60 Versmold | Clay |
| 10.07.19 | 1st round | Valentini Grammatikopoulou | Anastasiya Shoshyna | 6-2, 6-2 | | match details | ||
| 02.07.19 | 1st round | Eva Vedder | Valentini Grammatikopoulou | 6-2, 6-3 | | match details | W25 Den | Clay |
| 13.06.19 | 2nd round | Conny Perrin | Valentini Grammatikopoulou | 6-2, 6-2 | | match details | W60+H Rome | Clay |
| 11.06.19 | 1st round | Valentini Grammatikopoulou | Elisabetta Cocciaretto | 6-4, 6-4 | | match details | ||
| 24.05.19 | qual. | Varvara Lepchenko | Valentini Grammatikopoulou | 6-2, 6-2 | | match details | Paris | Clay |
| 23.05.19 | q 2 | Valentini Grammatikopoulou | Heather Watson | 7-5, 6-76, 7-63 | | match details | ||
| 22.05.19 | q 1 | Valentini Grammatikopoulou | Kimberly Birrell | 6-2, 3-6, 6-4 | | match details | ||
| 15.05.19 | 1st round | Marie Bouzkova | Valentini Grammatikopoulou | 6-3, 6-2 | | match details | W60+H La | Clay |
| 02.05.19 | 2nd round | Katarina Zavatska | Valentini Grammatikopoulou | 6-4, 4-6, 6-2 | | match details | W60 Wiesbaden | Clay |
| 01.05.19 | 1st round | Valentini Grammatikopoulou | Julie Gervais | 6-3, 1-6, 6-4 | | match details | ||
| 20.04.19 | q 1 | Anna Zaja | Valentini Grammatikopoulou | 7-63, 7-68 | | match details | Stuttgart | Clay |
| 26.09.18 | 1st round | Andrea Gamiz | Valentini Grammatikopoulou | 3-6, 6-4, 6-2 | | match details | Valencia | Clay |
| 06.09.18 | 2nd round | Kaja Juvan | Valentini Grammatikopoulou | 6-3, 6-2 | | match details | Zagreb | Clay |
| 05.09.18 | 1st round | Valentini Grammatikopoulou | Lea Boskovic | 6-3, 7-65 | | match details | ||
| 31.08.18 | 1/4 | Jasmine Paolini | Valentini Grammatikopoulou | 6-2, 6-3 | | match details | Bagnatica | Clay |
| 29.08.18 | 2nd round | Valentini Grammatikopoulou | Marie Benoit | 7-66, 6-4 | | match details | ||
| 28.08.18 | 1st round | Valentini Grammatikopoulou | Camilla Scala | 4-6, 6-1, 6-1 | | match details | ||
| 24.07.18 | 1st round | Varvara Flink | Valentini Grammatikopoulou | 6-2, 3-6, 6-3 | | match details |  Moscow | Clay |
| 23.07.18 | qual. | Valentini Grammatikopoulou | Anastasia Gasanova | 6-4, 6-3 | | match details | ||
| 22.07.18 | q 1 | Valentini Grammatikopoulou | Jessica Pieri | 6-2, 6-4 | | match details | ||
| 10.07.18 | 1st round | Montserrat Gonzalez | Valentini Grammatikopoulou | 4-6, 6-4, 6-4 | | match details | Getxo | Clay |
| 07.07.18 | 1/2 | Valeriya Strakhova | Valentini Grammatikopoulou | 3-6, 6-4, 6-4 | | match details | Denain | Clay |
| 06.07.18 | 1/4 | Valentini Grammatikopoulou | Anna Danilina | 6-4, 7-65 | | match details | ||
| 05.07.18 | 2nd round | Valentini Grammatikopoulou | Alice Rame | 7-65, 2-6, 6-2 | | match details | ||
| 04.07.18 | 1st round | Valentini Grammatikopoulou | Anna-Giulia Remondina | 7-66, 6-73, 6-2 | | match details | ||
| 24.05.18 | q 2 | Anna Kalinskaya | Valentini Grammatikopoulou | 3-6, 6-1, 6-2 | | match details | Paris | Clay |
| 23.05.18 | q 1 | Valentini Grammatikopoulou | Sofya Zhuk | 6-1, 1-6, 7-66 | | match details | ||
| 18.05.18 | 1/4 | Quirine Lemoine | Valentini Grammatikopoulou | 6-2, 6-4 | | match details | Saint Gaudens | Clay |
| 17.05.18 | 2nd round | Valentini Grammatikopoulou | Richel Hogenkamp | 7-63, 6-1 | | match details | ||
| 16.05.18 | 1st round | Valentini Grammatikopoulou | Kimberly Birrell | 4-6, 7-5, 6-2 | | match details | ||
| 12.04.18 | 2nd round | Johanna Larsson | Valentini Grammatikopoulou | 4-6, 6-4, 6-4 | | match details | Bogota | Clay |
| 11.04.18 | 1st round | Valentini Grammatikopoulou | Miyu Kato | 5-7, 6-4, 6-4 | | match details | ||
| 08.04.18 | qual. | Valentini Grammatikopoulou | Irina Khromacheva | 7-64, 7-65 | | match details | ||
| 07.04.18 | q 1 | Valentini Grammatikopoulou | Tereza Mrdeza | 4-6, 6-4, 6-3 | | match details | ||
| 07.09.17 | 2nd round | Jaqueline Cristian | Valentini Grammatikopoulou | 6-2, 6-3 | | match details |  Sofia | Clay |
| 06.09.17 | 1st round | Valentini Grammatikopoulou | Cristina Dinu | 6-4, 5-7, 6-2 | | match details | ||
| 16.07.17 | qual. | Tereza Smitkova | Valentini Grammatikopoulou | 6-75, 7-5, 6-1 | | match details | Gstaad | Clay |
| 15.07.17 | q 1 | Valentini Grammatikopoulou | Cornelia Lister | 6-3, 6-3 | | match details | ||
| 09.07.17 | fin | Arantxa Rus | Valentini Grammatikopoulou | 3-6, 6-2, 6-3 | | match details | Middelburg | Clay |
| 08.07.17 | 1/2 | Valentini Grammatikopoulou | Dejana Radanovic | 4-6, 6-4, 7-62 | | match details | ||
| 07.07.17 | 1/4 | Valentini Grammatikopoulou | Zoe Hives | 6-4, 6-1 | | match details | ||
| 06.07.17 | 2nd round | Valentini Grammatikopoulou | Helene Scholsen | 6-4, 6-3 | | match details | ||
| 04.07.17 | 1st round | Valentini Grammatikopoulou | Naiktha Bains | 7-64, 6-4 | | match details | ||
| 25.05.17 | q 2 | Jil Teichmann | Valentini Grammatikopoulou | 6-0, 6-2 | | match details | Paris | Clay |
| 23.05.17 | q 1 | Valentini Grammatikopoulou | Lizette Cabrera | 6-4, 6-3 | | match details | ||
| 20.05.17 | 1/2 | Richel Hogenkamp | Valentini Grammatikopoulou | 6-4, 6-3 | | match details | Saint Gaudens | Clay |
| 19.05.17 | 1/4 | Valentini Grammatikopoulou | Irina Khromacheva | 6-1, 2-2, Irina Khromacheva - retired | | match details | ||
| 17.05.17 | 2nd round | Valentini Grammatikopoulou | Ipek Soylu | 6-3, 6-3 | | match details | ||
| 16.05.17 | 1st round | Valentini Grammatikopoulou | Amandine Hesse | 7-63, 7-5 | | match details | ||
| 27.04.17 | 1/4 | Zarina Diyas | Valentini Grammatikopoulou | 6-3, 6-1 | | match details |  Anning | Clay |
| 26.04.17 | 2nd round | Valentini Grammatikopoulou | Jacqueline Cako | 6-4, 2-6, 6-1 | | match details | ||
| 23.04.17 | 1st round | Valentini Grammatikopoulou | Riko Sawayanagi | 6-2, 2-0, Riko Sawayanagi - retired | | match details | ||
| 28.03.17 | 1st round | Kathinka Von Deichmann | Valentini Grammatikopoulou | 7-5, 6-2 | | match details | Santa Margherita | Clay |
| 22.03.17 | 1st round | Marta Paigina | Valentini Grammatikopoulou | 7-63, 6-1 | | match details | Santa Margherita | Clay |
| 11.12.16 | fin | Valentini Grammatikopoulou | Jelena Simic | 6-1, 6-3 | | match details | Hammamet | Clay |
| 10.12.16 | 1/4 | Valentini Grammatikopoulou | Dalila Spiteri | 7-63, 6-2 | | match details | ||
| 10.12.16 | 1/2 | Valentini Grammatikopoulou | Carolina Meligeni Alves | 7-5, 6-4 | | match details | ||
| 09.12.16 | 2nd round | Valentini Grammatikopoulou | Nuria Brancaccio | 7-5, 6-1 | | match details | ||
| 06.12.16 | 1st round | Valentini Grammatikopoulou | Andreea Rosca | 6-1, 6-4 | | match details | ||
| 24.11.16 | 2nd round | Quirine Lemoine | Valentini Grammatikopoulou | 5-7, 6-3, 6-2 | | match details | Valencia | Clay |
| 23.11.16 | 1st round | Valentini Grammatikopoulou | Akgul Amanmuradova | 1-6, 6-2, 7-60 | | match details | ||
| 07.09.16 | 1st round | Jessica Pieri | Valentini Grammatikopoulou | 6-3, 7-5 | | match details | Sofia | Clay |
| 27.08.16 | fin | Anna Kalinskaya | Valentini Grammatikopoulou | 6-4, 1-6, 6-1 | | match details |  Kharkiv | Clay |
| 26.08.16 | 1/2 | Valentini Grammatikopoulou | Ganna Poznikhirenko | 2-0, Ganna Poznikhirenko - retired | | match details | ||
| 25.08.16 | 1/4 | Valentini Grammatikopoulou | Anastasiya Komardina | 5-7, 7-65, 6-3 | | match details | ||
| 24.08.16 | 2nd round | Valentini Grammatikopoulou | Ksenia Palkina | 6-3, 6-2 | | match details | ||
| 23.08.16 | 1st round | Valentini Grammatikopoulou | Veronika Kapshay | 6-2, 6-4 | | match details | ||
| 08.08.16 | 1st round | Elyne Boeykens | Valentini Grammatikopoulou | 7-5, 6-75, 6-2 | | match details | Koksijde | Clay |
| 28.07.16 | 2nd round | Richel Hogenkamp | Valentini Grammatikopoulou | 6-1, 1-6, 6-3 | | match details | Horb | Clay |
| 26.07.16 | 1st round | Valentini Grammatikopoulou | Katarzyna Kawa | 6-2, 6-3 | | match details | ||
| 21.07.16 | 2nd round | Dalila Jakupovic | Valentini Grammatikopoulou | 6-0, 6-71, 6-2 | | match details | Darmstadt | Clay |
| 20.07.16 | 1st round | Valentini Grammatikopoulou | Conny Perrin | 6-4, 6-2 | | match details | ||
| 09.07.16 | q 1 | Misa Eguchi | Valentini Grammatikopoulou | 6-4, 6-1 | | match details | Bucharest | Clay |
| 03.07.16 | fin | Quirine Lemoine | Valentini Grammatikopoulou | 6-2, 7-5 | | match details | Middelburg | Clay |
| 02.07.16 | 1/2 | Valentini Grammatikopoulou | Bibiane Schoofs | 6-2, 6-3 | | match details | ||
| 01.07.16 | 1/4 | Valentini Grammatikopoulou | Richel Hogenkamp | 6-3, 4-6, 6-3 | | match details | ||
| 29.06.16 | 2nd round | Valentini Grammatikopoulou | Irene Burillo Escorihuela | 6-4, 6-3 | | match details | ||
| 28.06.16 | 1st round | Valentini Grammatikopoulou | Eliessa Vanlangendonck | 6-2, 6-2 | | match details | ||
| 24.06.16 | 1/4 | Vivian Heisen | Valentini Grammatikopoulou | 6-71, 7-63, 7-62 | | match details | Breda | Clay |
| 23.06.16 | 2nd round | Valentini Grammatikopoulou | Petra Krejsova | 6-3, 6-4 | | match details | ||
| 22.06.16 | 1st round | Valentini Grammatikopoulou | Charlotte Swaans | 6-1, 6-0 | | match details | ||
| 18.06.16 | fin | Valentini Grammatikopoulou | Anna Kalinskaya | 6-3, 4-1, Anna Kalinskaya - retired | | match details |  Minsk | Clay |
| 17.06.16 | 1/2 | Valentini Grammatikopoulou | Iryna Shymanovich | 6-3, 6-4 | | match details | ||
| 16.06.16 | 1/4 | Valentini Grammatikopoulou | Vera Lapko | 3-2, Vera Lapko - retired | | match details | ||
| 15.06.16 | 2nd round | Valentini Grammatikopoulou | Laura Pigossi | 6-0, 6-1 | | match details | ||
| 14.06.16 | 1st round | Valentini Grammatikopoulou | Varvara Flink | 6-2, 6-4 | | match details | ||
| 08.06.16 | 2nd round | Vera Lapko | Valentini Grammatikopoulou | 7-67, 6-2 | | match details | Minsk | Clay |
| 07.06.16 | 1st round | Valentini Grammatikopoulou | Aryna Sabalenka | 2-6, 6-0, 7-5 | | match details | ||
| 12.05.16 | 2nd round | Daniela Seguel | Valentini Grammatikopoulou | 6-1, 6-2 | | match details | La Marsa | Clay |
| 11.05.16 | 1st round | Valentini Grammatikopoulou | Britt Geukens | 7-5, 6-3 | | match details | ||
| 02.05.16 | qual. | Maria Marfutina | Valentini Grammatikopoulou | 6-4, 6-3 | | match details | Tunis | Clay |
| 02.05.16 | q 2 | Valentini Grammatikopoulou | Vanda Lukacs | 7-65, 6-4 | | match details | ||
| 27.04.16 | 1st round | Elena Gabriela Ruse | Valentini Grammatikopoulou | 6-2, 6-2 | | match details | Chiasso | Clay |
| 16.04.16 | 1/2 | Alice Bacquie | Valentini Grammatikopoulou | 6-1, 6-1 | | match details | Hammamet | Clay |
| 15.04.16 | 1/4 | Valentini Grammatikopoulou | Ines Ibbou | 6-1, 7-5 | | match details | ||
| 14.04.16 | 2nd round | Valentini Grammatikopoulou | Natalija Stevanovic | 6-2, 6-2 | | match details | ||
| 13.04.16 | 1st round | Valentini Grammatikopoulou | Mathilda Malm | 6-3, 6-2 | | match details | ||
| 09.04.16 | 1/2 | Irina Maria Bara | Valentini Grammatikopoulou | 6-2, 6-2 | | match details | Hammamet | Clay |
| 08.04.16 | 2nd round | Valentini Grammatikopoulou | Irina Fetecau | 4-6, 6-1, 6-1 | | match details | ||
| 08.04.16 | 1/4 | Valentini Grammatikopoulou | Milana Spremo | 6-4, 6-3 | | match details | ||
| 05.04.16 | 1st round | Valentini Grammatikopoulou | Louise Lampla | 6-1, 6-0 | | match details | ||
| 17.03.16 | 2nd round | Giorgia Marchetti | Valentini Grammatikopoulou | 6-72, 6-2, 6-1 | | match details | Gonesse | Clay |
| 16.03.16 | 1st round | Valentini Grammatikopoulou | Kelia Le Bihan | 2-6, 6-2, 7-64 | | match details | ||
| 24.08.15 | 1/4 | Valentini Grammatikopoulou | Suzan Lamens | 6-2, 6-74, 6-0 | | match details | Rotterdam | Clay |
| 24.08.15 | fin | Chayenne Ewijk | Valentini Grammatikopoulou | 7-63, 6-3 | | match details | ||
| 24.08.15 | 1/2 | Valentini Grammatikopoulou | Sviatlana Pirazhenka | 4-6, 6-3, 6-1 | | match details | ||
| 24.08.15 | 1st round | Valentini Grammatikopoulou | Janine Hemmes | 6-2, 5-7, 6-2 | | match details | ||
| 24.08.15 | 2nd round | Valentini Grammatikopoulou | Karin Kennel | 6-2, 6-2 | | match details | ||
| 17.08.15 | fin | Valentini Grammatikopoulou | Katharina Lehnert | 7-62, 6-3 | | match details | Oldenzaal | Clay |
| 17.08.15 | 2nd round | Valentini Grammatikopoulou | Steffi Distelmans | 6-2, 6-2 | | match details | ||
| 17.08.15 | 1/4 | Valentini Grammatikopoulou | Sviatlana Pirazhenka | 6-1, 4-6, 6-1 | | match details | ||
| 17.08.15 | qual. | Valentini Grammatikopoulou | Sheila Moradian | 6-3, 6-2 | | match details | ||
| 17.08.15 | 1/2 | Valentini Grammatikopoulou | Camila Giangreco Campiz | 6-4, 4-6, 7-5 | | match details | ||
| 17.08.15 | 1st round | Valentini Grammatikopoulou | Katharina Hering | 2-6, 6-4, 6-1 | | match details | ||
| 03.08.15 | qual. | Valentini Grammatikopoulou | Yuuki Tanaka | 6-3, 6-3 | | match details | Bad Saulgau | Clay |
| 03.08.15 | 1st round | Sophia Kovalets | Valentini Grammatikopoulou | 6-74, 6-4, 6-1 | | match details | ||
| 03.08.15 | q 1 | Valentini Grammatikopoulou | Anna Gabric | 6-76, 6-4, 7-65 | | match details | ||
| 27.07.15 | q 1 | Erika Vogelsang | Valentini Grammatikopoulou | 5-2, Valentini Grammatikopoulou - retired | | match details | Horb | Clay |
| 06.07.15 | 1st round | Richel Hogenkamp | Valentini Grammatikopoulou | 4-6, 6-4, 6-4 | | match details | Versmold | Clay |
| 06.07.15 | q 2 | Valentini Grammatikopoulou | Victoria Smirnova | 6-2, 4-6, 6-3 | | match details | ||
| 06.07.15 | qual. | Valentini Grammatikopoulou | Martina Borecka | 7-64, 4-6, 6-4 | | match details | ||
| 06.07.15 | q 1 | Valentini Grammatikopoulou | Natalia Siedliska | 6-1, 7-5 | | match details | ||
| 22.06.15 | 1st round | Valentini Grammatikopoulou | Nikki Luttikhuis | 2-6, 6-4, 6-4 | | match details | Breda | Clay |
| 22.06.15 | 2nd round | Pia Konig | Valentini Grammatikopoulou | 6-2, 6-0 | | match details | ||
| 15.06.15 | 1st round | Valentini Grammatikopoulou | Danijela Tomic | 6-2, 6-4 | | match details | Nis | Clay |
| 15.06.15 | 2nd round | Valentini Grammatikopoulou | Jovana Vukovic | 6-1, 6-0 | | match details | ||
| 15.06.15 | 1/4 | Dejana Radanovic | Valentini Grammatikopoulou | 6-3, 6-0 | | match details | ||
| 27.04.15 | qual. | Carolin Daniels | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | Wiesbaden | Clay |
| 27.04.15 | q 1 | Valentini Grammatikopoulou | Natasha Fourouclas | 6-3, 7-5 | | match details | ||
| 16.03.15 | 1st round | Sina Haas | Valentini Grammatikopoulou | 6-1, 6-1 | | match details | Gonesse | Clay |
| 09.03.15 | 1st round | Alena Tarasova | Valentini Grammatikopoulou | 6-3, 6-3 | | match details | Amiens | Clay |
| 08.09.14 | 1/4 | Valentini Grammatikopoulou | Ema Polic | 5-2, Ema Polic - retired | | match details | Vrnjacka Banja | Clay |
| 08.09.14 | 1/2 | Valentini Grammatikopoulou | Julia Stamatova | 6-3, 6-1 | | match details | ||
| 08.09.14 | 1st round | Valentini Grammatikopoulou | Dajana Dukic | 6-4, 6-3 | | match details | ||
| 08.09.14 | fin | Valentini Grammatikopoulou | Dea Herdzelas | 1-6, 6-3, 7-65 | | match details | ||
| 08.09.14 | 2nd round | Valentini Grammatikopoulou | Anna Makhorkina | 6-2, 6-3 | | match details | ||
| 25.08.14 | 1/2 | Quirine Lemoine | Valentini Grammatikopoulou | 7-5, 6-1 | | match details | Rotterdam | Clay |
| 25.08.14 | 1/4 | Valentini Grammatikopoulou | Nicola Geuer | 6-2, 6-4 | | match details | ||
| 25.08.14 | 1st round | Valentini Grammatikopoulou | Steffi Distelmans | 6-2, 6-4 | | match details | ||
| 25.08.14 | 2nd round | Valentini Grammatikopoulou | Katharina Hering | 6-3, 6-3 | | match details | ||
| 14.07.14 | 2nd round | Valentini Grammatikopoulou | Sofie Oyen | 6-4, 6-76, 6-2 | | match details | Knokke | Clay |
| 14.07.14 | 1/4 | Kelly Versteeg | Valentini Grammatikopoulou | 6-1, 7-64 | | match details | ||
| 14.07.14 | 1st round | Valentini Grammatikopoulou | Alice Rame | 6-4, 6-2 | | match details | ||
| 07.07.14 | q 1 | Valentini Grammatikopoulou | Michelle Van Lier | 6-2, 6-2 | | match details | Aschaffenburg | Clay |
| 07.07.14 | qual. | Yuuki Tanaka | Valentini Grammatikopoulou | 6-2, 6-2 | | match details | ||
| 07.07.14 | q 2 | Valentini Grammatikopoulou | Natalia Orlova | 1-6, 6-3, 6-0 | | match details | ||
| 30.06.14 | 1st round | Valentini Grammatikopoulou | Helene Scholsen | 6-1, 6-3 | | match details | Brussels | Clay |
| 30.06.14 | 1/4 | Klaartje Liebens | Valentini Grammatikopoulou | 1-6, 6-3, 7-610 | | match details | ||
| 30.06.14 | 2nd round | Valentini Grammatikopoulou | Deborah Kerfs | 6-3, 6-4 | | match details | ||
| 23.06.14 | qual. | Valentini Grammatikopoulou | Elke Tiel | 6-0, 6-1 | | match details | Breda | Clay |
| 23.06.14 | 2nd round | Beatriz Haddad Maia | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | ||
| 23.06.14 | 1st round | Valentini Grammatikopoulou | Isabella Shinikova | 6-4, 6-2 | | match details | ||
| 23.06.14 | q 2 | Valentini Grammatikopoulou | Michele Erkens | 6-1, 6-1 | | match details | ||
| 09.06.14 | q 2 | Valentini Grammatikopoulou | Caroline Werner | 6-3, 6-3 | | match details | Essen | Clay |
| 09.06.14 | qual. | Tayisiya Morderger | Valentini Grammatikopoulou | 6-3, 6-3 | | match details | ||
| 26.05.14 | q 1 | Ana Oparenovic | Valentini Grammatikopoulou | 6-0, 6-4 | | match details | Maribor | Clay |
| 19.05.14 | 1st round | Manca Pislak | Valentini Grammatikopoulou | 6-0, 6-1 | | match details | Velenje | Clay |
| 03.03.14 | 1st round | Valentini Grammatikopoulou | Steffi Carruthers | 6-3, 6-4 | | match details | Gainesville | Clay |
| 03.03.14 | 2nd round | Sina Haas | Valentini Grammatikopoulou | 6-4, 6-3 | | match details | ||
| 20.01.14 | q 1 | Naomi Osaka | Valentini Grammatikopoulou | 6-0, 7-65 | | match details | Daytona Beach | Clay |
| 13.01.14 | q 2 | Jennifer Elie | Valentini Grammatikopoulou | 7-5, 6-3 | | match details | Port St. | Clay |
| 13.01.14 | q 1 | Valentini Grammatikopoulou | Madison Bourguignon | 6-4, 6-1 | | match details | ||
| 06.01.14 | q 1 | Kristina Mathis | Valentini Grammatikopoulou | 6-3, 2-6, 6-3 | | match details | Vero Beach | Clay |
| 09.09.13 | q 1 | Valentini Grammatikopoulou | Victoria Ocheva | 6-0, 6-2 | | match details | Sofia | Clay |
| 09.09.13 | qual. | Gabriela Lee | Valentini Grammatikopoulou | 7-5, 6-4 | | match details | ||
| 02.09.13 | 1/4 | Xenia Knoll | Valentini Grammatikopoulou | 6-1, 6-1 | | match details | Belgrade | Clay |
| 02.09.13 | 1st round | Valentini Grammatikopoulou | Cristina Adamescu | 6-3, 7-62 | | match details | ||
| 02.09.13 | 2nd round | Valentini Grammatikopoulou | Marija Mastilovic | 6-3, 6-4 | | match details | ||
| 26.08.13 | 1st round | Valentini Grammatikopoulou | Nikolina Jovic | 7-63, 6-76, 6-3 | | match details | Belgrade | Clay |
| 26.08.13 | 2nd round | Dunja Stamenkovic | Valentini Grammatikopoulou | 6-2, 6-3 | | match details | ||
| 05.08.13 | 1/4 | Valentini Grammatikopoulou | Milana Spremo | 7-5, 1-6, 6-1 | | match details | Pirot | Clay |
| 05.08.13 | 1/2 | Valentini Grammatikopoulou | Vladica Babic | 6-3, 6-1 | | match details | ||
| 05.08.13 | 1st round | Valentini Grammatikopoulou | Dajana Dukic | 6-4, 6-2 | | match details | ||
| 05.08.13 | fin | Valentini Grammatikopoulou | Eva Wacanno | 6-1, 6-4 | | match details | ||
| 05.08.13 | 2nd round | Valentini Grammatikopoulou | Milica Sljukic | 6-1, 6-2 | | match details | ||
| 22.07.13 | 1st round | Valentini Grammatikopoulou | Rosalie Willig | 6-3, 6-4 | | match details | Horb | Clay |
| 22.07.13 | 2nd round | Petra Krejsova | Valentini Grammatikopoulou | 6-2, 6-4 | | match details | ||
| 15.07.13 | 1st round | Natalie Proese | Valentini Grammatikopoulou | 5-7, 6-1, 7-65 | | match details | Darmstadt | Clay |
| 24.06.13 | 1st round | Anastasiya Vasylyeva | Valentini Grammatikopoulou | 6-3, 6-1 | | match details | Breda | Clay |
| 18.05.13 | q 1 | Jennifer Elie | Valentini Grammatikopoulou | 6-4, 6-1 | | match details | Brussels | Clay |
| 17.12.12 | 1st round | Valentini Grammatikopoulou | Margarida Moura | 6-4, 6-2 | | match details |  Antalya | Clay |
| 17.12.12 | q 2 | Valentini Grammatikopoulou | Darya Chernetsova | 4-6, 6-1, 6-4 | | match details | ||
| 17.12.12 | 2nd round | Isabella Shinikova | Valentini Grammatikopoulou | 7-64, 6-3 | | match details | ||
| 17.12.12 | qual. | Valentini Grammatikopoulou | Aliona Bolsova | 6-3, 6-1 | | match details | ||
| 10.12.12 | qual. | Valentini Grammatikopoulou | Irina Maria Bara | 6-1, 6-3 | | match details | Antalya | Clay |
| 10.12.12 | 1st round | Magdalena Frech | Valentini Grammatikopoulou | 7-5, 6-1 | | match details | ||
| 10.12.12 | q 1 | Valentini Grammatikopoulou | Sofie Uzdina | 6-2, 6-1 | | match details | ||
| 10.12.12 | q 2 | Valentini Grammatikopoulou | Rio Kitagawa | 6-3, 4-2, Rio Kitagawa - retired | | match details | ||
| 03.09.12 | qual. | Valentini Grammatikopoulou | Marine Fontaine | 6-0, 6-2 | | match details | Engis | Clay |
| 03.09.12 | 1st round | Patrycja Sanduska | Valentini Grammatikopoulou | 6-4, 6-4 | | match details | ||
| 03.09.12 | q 1 | Valentini Grammatikopoulou | Laura Van Der Haegen | 6-0, 6-1 | | match details | ||
| 27.08.12 | q 2 | Anouk Tigu | Valentini Grammatikopoulou | 6-0, 6-2 | | match details | Rotterdam | Clay |
| 27.08.12 | q 1 | Valentini Grammatikopoulou | Nora Niedmers | 6-2, 6-4 | | match details | ||
| 20.08.12 | qual. | Yana Morderger | Valentini Grammatikopoulou | 6-2, 6-3 | | match details | Enschede | Clay |
| 20.08.12 | q 2 | Valentini Grammatikopoulou | Anna Katalina Alzate Esmurzaeva | 6-2, 6-3 | | match details |
